Diagenesis and Authigenic Magnetic Minerals

Pyrrhotite

Pyrrhotite (salmon-coloured, Fe7S8) enclosed in pyrite (yellow). The margins of the tabular pyrrhotite crystals show replacement by pyrite. The pyrrhotite formed as a result of hydrocarbon seepage. XRD and thermomagnetic measurements confirm the mineralogy (width of image= 320mm) {RL optical, oil immersion} Cement oil field, Oklahoma [R.L. Reynolds]
Pyrrhotite blades within a calcite matrix {RL optical, oil immersion} [R.L. Reynolds]
bladed Pyrrhotite crystal (PO) (scale bar= 4mm) {SEM} Cement oil field, Oklahoma. [R.L. Reynolds]
Pyrrhotite (Fe7S8, darker; PO) intergrown with pyrite (white;PY), with later formation of marcasite (MC) on the periphery. Composite grains such as this my represent a late stage in the production of FeS2 phases. In this oil field pyrrhotite forms approximately 0 to 5% of the total FeS2 (width of image= 320mm) {RL optical, oil immersion} Cement oil field, Oklahoma. [R.L. Reynolds]

Greigite

Detrital plant fragment. The cell lumens of this fragment contain sulfide, with at least some of it being greigite. Interpretation based on accompanying XRD and magnetic properties (width of image= 320mm) {RL optical, oil immersion} [R.L. Reynolds]
Grain morphologies of greigite particles less than 0.1mm in size. Interpretation based on x-ray diffraction and magnetic measurements (width of micrograph =4.5mm ){magnetic extract, TEM} Quaternary, Sheringham clays, Norfolk,UK [D. Hallam]
Magnetic sulphide grain (Fe + S from EDS analysis) inferred to contain or be greigite. The sulphide appears to be a replacement of an organic structure and sits on a plant fragment. The magnetic extract was highly unstable and became non-magnetic after a few days, due to the oxidation of the greigite {magnetic extract, SEM} Iron age (~300-100AD) ditch, Yarnton, Somerset, UK. [M.W. Hounslow]
Small particles of Fe plus S (interpreted as greigite) on a large octahedra of pyrite (scale bar = 4mm) {magnetic extract , SEM, EDS} Ninuluk-Seebee Formation, Cretaceous, Alaska {R.L. Reynolds]
Björkeröds- Sweden Individual single-domain greigite crystals. Greigite was confirmed by XRD and EDS. (scale bar = 2mm) {magnetic extract , XRD, SEM, EDS} Björkeröds
Mosse, southern Sweden {I. Snowball]

Haematite

Martite (titanomagnetite replaced by haematite). The typical trellis texture of haematite replaced titanomagnetite is accentuated by voids, indicating some removal of the Fe from the original grain. Few thin vestiges of darker ilmenite (FeTiO3) emphasis the trellis texture (grain is 300 mm across) {Optical, Oil immersion} Miocene Catahoula sandstone [R.L. Reynolds]
Polycrystalline haematite displaying trellis textured martite, indicated by the optical anisotropy of the haematite crystals. (grain is 90 mm across) {optical, cross nicols} Permian, Cutler Fm, Utah [R.L. Reynolds]
Biotite grain which has been partially altered to specular haematite. The haematite has formed parallel to the cleavage planes of the biotite. Note the blood-red internal reflections of fine-grained heamatite grains on the periphery of the altered biotite (grain 100 mm across) {optical} Permian, Cutler Fm, Utah [R.L. Reynolds]
Clusters of specular haematite composed of interlocking haematite blades. The blades sit on top of smectite {SEM} Permian, Cutler Fm, Utah [R.L. Reynolds]

Goethite

Pyrite cube showing complete replacement by Fe-oxyhydroxides (mostly goethite ?). The variable reflectance of the Fe-oxyhydroxides is probably due both to an admixture of lepidocrocite and other oxyhydroxides and also to crystallite packing density. (width of image 160 mm) {RL optical}. [R.L. Reynolds]
Pyrite (white) partially replaced around grain periphery and along cracks by Fe-oxyhydroxides (probably mostly goethite). (height of image 207mm) {RL optical} Heavy mineral seperate, modern beach sand, location unknown. [M.W. Hounslow]

Pyritisation

Pyrite replacing titanomagnetite, with the pyrite mimicking the 111 lattice planes of the host. (width of image 100 mm) {RL optical} [L.Owens]
Titanomagnetite composed of relict magnetite (MT) and ilmenite (ILM) has been replaced by pyrite (white). Marcasite (MC) occurs as partial overgrowths on the pyrite. (width of image = 160mm) {RL Optical, oil immersion} Miocene Catahoula Sandstone, Texas [R.L. Reynolds]
Replacement of titanohaematite (gray) by pyrite (white) on grain margins and along fractures. (width of full photo= 160mm) {RL Optical, oil immersion} Miocene Catahoula Sandstone, Texas [R.L. Reynolds]
Fe and S spheres (interpreted as pyrite) on an Fe-Ti grain (interpreted as titanomagnetite), which shows strong dissolution. The upstanding ridges may be Ilmenite intergrowths, which are more resistant to dissolution than the intervening Fe-rich titanomagnetite. {SEM, EDS} Quaternary, Great barrier Reef, ODP hole 864, Australia. [A.Perkins]

 

Dissolution of Fe-Oxides

The skeletal trellis network of TiO2 platelets is all that remains of a former probably titanomagnetite grain, in which the Fe has been leached by pore fluids. The white internal reflections of the TIO2 minerals (rutile ?) around the grain are a typical product of Fe-dissolution reactions in sediments. {RL Optical, oil immersion} [R.L. Reynolds]
A framework of TiO2 grains forming a trellis-like texture (reflects the exsolution texture of the former grain), which is interpreted as a relict of a former ilmenite grain. The Fe in the ilmenite has been largely removed by aggressive pore fluids. {SEM, EDS} Lunde Formation, Beryl Field, North Sea, UK. [M.W. Hounslow]